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Last updated

26 February 2026

pptx, 7.97 MB
pptx, 7.97 MB

This PowerPoint lesson explains sigma (σ) and pi (π) bonds in terms of atomic orbital overlap, helping Higher Level IBDP Chemistry students understand the structure and reactivity of covalent molecules. Designed for first assessment 2025, it builds the conceptual foundation required to analyse single, double and triple bonds in both organic and inorganic compounds.

A sigma bond is formed by head-on overlap of atomic orbitals along the internuclear axis, while a pi bond forms from sideways overlap of parallel p orbitals above and below the bond axis. This lesson clearly defines these bond types and links them to electron density distribution, bond strength and molecular rotation.

Students explore how σ bonds can arise from s–s, s–p or p–p overlap, and why every single bond contains one sigma bond. The structure of multiple bonds is then developed: a double bond consists of one σ and one π bond, and a triple bond contains one σ and two π bonds. Worked examples using ethane, ethene and ethyne help students visualise bonding in organic molecules, while inorganic examples such as ozone introduce the connection between π bonding and resonance.

The lesson also compares bond enthalpies, explaining why π bonds are weaker than σ bonds and therefore more reactive. The restriction of rotation around double bonds is linked directly to the presence of a π bond, reinforcing structure–reactivity relationships.

Starter activities, clear diagrams, structured explanations and practice questions are included, making this resource suitable for Higher Level teaching, consolidation or revision.

File type included: PowerPoint (.pptx)
Last updated: January 2026 – bonding diagrams refined, resonance links strengthened, and HL scope checked against the 2025 IB Chemistry syllabus.

Get this resource as part of a bundle and save up to 33%

A bundle is a package of resources grouped together to teach a particular topic, or a series of lessons, in one place.

Bundle

BUNDLE S2.2 The Covalent Model HL Only Content (IBDP Chemistry)

This comprehensive bundle of PowerPoints covers the Higher Level content of Topic 2.2 The Covalent Model for IBDP Chemistry (first examination 2025). It develops deep conceptual understanding of resonance, benzene, expanded octets, formal charge, sigma and pi bonding, and hybridisation in a structured, exam-focused sequence. The covalent model explains how atoms share electrons to form molecules, and at HL it extends beyond simple Lewis structures to include delocalisation, orbital overlap and electron-domain analysis. This bundle is designed to build that progression logically — from resonance structures through to hybridisation and aromatic stability — ensuring students can connect Lewis formulas, VSEPR theory, bond order, formal charge and orbital theory. Included lessons: • Resonance Structures – electron delocalisation, bond order, ozone, carbonate, nitrate and resonance hybrids • Benzene – historical models, bond length evidence, hydrogenation data, resonance energy and aromatic stability • Expanded Octets & VSEPR – five and six electron domains, trigonal bipyramidal, T-shaped, octahedral, square planar • Formal Charge – selecting preferred Lewis structures and evaluating charge distribution • Sigma and Pi Bonds – orbital overlap, bond strength, restricted rotation, delocalised π systems • Hybridisation – sp, sp², sp³ bonding, excitation, molecular geometry and benzene delocalisation Throughout the bundle, students analyse physical and chemical evidence, compare alternative structures, and apply exam-style reasoning. Clear worked examples, mini-whiteboard tasks, structured explanations and practice questions are included in each lesson. This resource is ideal for teaching, consolidation or HL revision and aligns fully with the 2025 IB Chemistry syllabus. File type included: Multiple PowerPoint files (.pptx) Last updated: January 2026 – sequencing refined and cross-links between resonance, hybridisation and benzene strengthened for conceptual clarity.

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5

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faye_hadlington123

4 months ago
5

Another fantastic lesson from this teacher. Love getting resources from here. Saves me so much planning time.

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